The removal of selenite (SeO32-) was investigated using a new polymer/ hydrated iron oxide composites. These composites may have potential applications in reducing or entirely eliminating selenite from contaminated drinking water or industrial wastewaters, especially those from flue gas desulphurization. Commercially available ion exchange resins were irreversibly impregnated by hydrated iron oxide to increase selenite removal from model water solutions simulated contaminated drinking water containing various accompanying anions such as nitrates and sulfates, that may affect the sorption of selenite. By batch experiments the effect of the accompanying ions and pH of the input model water solutions on the selenite removal was investigated. The results of the measurements show that the most suitable sorbents for the removal of selenite from aqueous solutions are macroporous sorbents, which contained more hydrated iron oxide in their structure and thus showed higher selenite removal efficiency than gelular composites. It was found that the prepared composites achieved the highest efficiency of removed selenite at low pH, whereas the optimum pH for commercially available sorbents was in the neutral range. Reduced selenite removal efficiencies from the solution were primarily observed for macroporous composites in the presence of sulfates, either alone or when mixed with nitrates.
The paper presents a study of processing peat into fuel. The drying kinetics of composite raw materials based on peat, aged silt deposits, solid peat residues after extraction and corn crop residues were determined. The dependence of the drying optimization criterion on the moisture content of the material is investigated, which substantiates the effectiveness of the selected drying modes for composite raw materials. The heat of combustion of the composite raw material was determined, which is about 1.4 times higher than that of peat. Composite biofuel, as well as its components, were investigated using the methods of differential thermal analysis, which showed the temperature intervals and rate of dehydration, thermal decomposition of organic and mineral substances.